Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer: Fid-Bau Portal

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Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer

Karakhanov, E. A. / Boronoev, M. P. / Filippova, T. Yu. / Maksimov, A. L.

Abstract Guaiacol hydrogenation in an aqueous medium in the presence of a palladium catalyst supported on a mesoporous dendrimer-containing polymer and the effect of addition of sulfuric acid to the catalyst system have been studied. It has been found that the main hydrogenation product is 2-methoxycyclohexanol. After the addition of sulfuric acid to the catalyst system, the reaction mechanism significantly changes and cyclohexanol becomes the main hydrogenation product.

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Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer

Karakhanov, E. A. / Boronoev, M. P. / Filippova, T. Yu. / Maksimov, A. L.

Abstract Guaiacol hydrogenation in an aqueous medium in the presence of a palladium catalyst supported on a mesoporous dendrimer-containing polymer and the effect of addition of sulfuric acid to the catalyst system have been studied. It has been found that the main hydrogenation product is 2-methoxycyclohexanol. After the addition of sulfuric acid to the catalyst system, the reaction mechanism significantly changes and cyclohexanol becomes the main hydrogenation product.

Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer

Karakhanov, E. A. / Boronoev, M. P. / Filippova, T. Yu. / Maksimov, A. L.

Abstract Guaiacol hydrogenation in an aqueous medium in the presence of a palladium catalyst supported on a mesoporous dendrimer-containing polymer and the effect of addition of sulfuric acid to the catalyst system have been studied. It has been found that the main hydrogenation product is 2-methoxycyclohexanol. After the addition of sulfuric acid to the catalyst system, the reaction mechanism significantly changes and cyclohexanol becomes the main hydrogenation product.

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Title:

Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer

Contributors:

Karakhanov, E. A. (author) / Boronoev, M. P. (author) / Filippova, T. Yu. (author) / Maksimov, A. L. (author)

Published in:

Petroleum Chemistry ; 58 ; 407-411

Publication date:

2018-05-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544118050080

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

mesoporous polymer , hydrogenation , hybrid catalyst , guaiacol Chemistry , Industrial Chemistry/Chemical Engineering

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