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    Kinetic Modeling of the Palladium‐Catalyzed Isomerizing Methoxycarbonylation of 1‐Decene

    New search for: Gerlach, Martin
    New search for: Kirschtowski, Sabine
    New search for: Hamel, Christof

    The experimental and model‐based investigation of the palladium‐catalyzed methoxycarbonylation of 1‐decene using methanol and carbon monoxide is presented. The reaction was studied in a thermomorphic solvent system using the industrially applied ligand DTBPMB in order to describe the kinetics of the main and the most relevant side reactions. Based on a reaction analysis, kinetic models including main influencing variables were derived and successfully parametrized. Thus, inhibition effects of the substrate 1‐decene as well as carbon monoxide on the isomerization and methoxycarbonylation rate could be identified.

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    Kinetic Modeling of the Palladium‐Catalyzed Isomerizing Methoxycarbonylation of 1‐Decene

    New search for: Gerlach, Martin
    New search for: Kirschtowski, Sabine
    New search for: Hamel, Christof

    The experimental and model‐based investigation of the palladium‐catalyzed methoxycarbonylation of 1‐decene using methanol and carbon monoxide is presented. The reaction was studied in a thermomorphic solvent system using the industrially applied ligand DTBPMB in order to describe the kinetics of the main and the most relevant side reactions. Based on a reaction analysis, kinetic models including main influencing variables were derived and successfully parametrized. Thus, inhibition effects of the substrate 1‐decene as well as carbon monoxide on the isomerization and methoxycarbonylation rate could be identified.

    Access

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    Kinetic Modeling of the Palladium‐Catalyzed Isomerizing Methoxycarbonylation of 1‐Decene

    New search for: Gerlach, Martin
    New search for: Kirschtowski, Sabine
    New search for: Hamel, Christof

    The experimental and model‐based investigation of the palladium‐catalyzed methoxycarbonylation of 1‐decene using methanol and carbon monoxide is presented. The reaction was studied in a thermomorphic solvent system using the industrially applied ligand DTBPMB in order to describe the kinetics of the main and the most relevant side reactions. Based on a reaction analysis, kinetic models including main influencing variables were derived and successfully parametrized. Thus, inhibition effects of the substrate 1‐decene as well as carbon monoxide on the isomerization and methoxycarbonylation rate could be identified.

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    Title:

    Kinetic Modeling of the Palladium‐Catalyzed Isomerizing Methoxycarbonylation of 1‐Decene

    Contributors:

    Gerlach, Martin (author) / Kirschtowski, Sabine (author) / Seidel‐Morgenstern, Andreas (author) / Hamel, Christof (author)

    Published in:

    Chemie Ingenieur Technik ; 90 ; 673-678

    Publication date:

    2018-05-01

    Size:

    6 pages

    ISSN:

    0009-286X , 1522-2640

    DOI:

    https://doi.org/10.1002/cite.201700162

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    Alkene , Kinetic modeling , Homogeneous catalysis , Methoxycarbonylation , Palladium

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