Kinetics of the Rhodium‐Catalyzed Hydroaminomethylation of 1‐Decene in a Thermomorphic Solvent System: Fid-Bau Portal

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Kinetics of the Rhodium‐Catalyzed Hydroaminomethylation of 1‐Decene in a Thermomorphic Solvent System

Kortuz, Wieland / Kirschtowski, Sabine / Seidel‐Morgenstern, Andreas / Hamel, Christof

The homogenously rhodium‐catalyzed tandem reaction of the hydroaminomethylation of 1‐decene is investigated in a thermomorphic solvent system consisting of methanol and n‐dodecane with the ligand sulfoxantphos. The influence of temperature, pressure and catalyst concentration is studied experimentally as the basis for kinetic modeling and parameter estimation. A kinetic model for the hydroaminomethylation is developed by connecting and reparametrizing a mechanistic approach for the hydroformylation with a reductive amination model. Simulations and experimental data are in good agreement indicating the transferability of mechanistic kinetic models.

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Kinetics of the Rhodium‐Catalyzed Hydroaminomethylation of 1‐Decene in a Thermomorphic Solvent System

Kortuz, Wieland / Kirschtowski, Sabine / Seidel‐Morgenstern, Andreas / Hamel, Christof

The homogenously rhodium‐catalyzed tandem reaction of the hydroaminomethylation of 1‐decene is investigated in a thermomorphic solvent system consisting of methanol and n‐dodecane with the ligand sulfoxantphos. The influence of temperature, pressure and catalyst concentration is studied experimentally as the basis for kinetic modeling and parameter estimation. A kinetic model for the hydroaminomethylation is developed by connecting and reparametrizing a mechanistic approach for the hydroformylation with a reductive amination model. Simulations and experimental data are in good agreement indicating the transferability of mechanistic kinetic models.

Kinetics of the Rhodium‐Catalyzed Hydroaminomethylation of 1‐Decene in a Thermomorphic Solvent System

Kortuz, Wieland / Kirschtowski, Sabine / Seidel‐Morgenstern, Andreas / Hamel, Christof

The homogenously rhodium‐catalyzed tandem reaction of the hydroaminomethylation of 1‐decene is investigated in a thermomorphic solvent system consisting of methanol and n‐dodecane with the ligand sulfoxantphos. The influence of temperature, pressure and catalyst concentration is studied experimentally as the basis for kinetic modeling and parameter estimation. A kinetic model for the hydroaminomethylation is developed by connecting and reparametrizing a mechanistic approach for the hydroformylation with a reductive amination model. Simulations and experimental data are in good agreement indicating the transferability of mechanistic kinetic models.

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Title:

Kinetics of the Rhodium‐Catalyzed Hydroaminomethylation of 1‐Decene in a Thermomorphic Solvent System

Contributors:

Kortuz, Wieland (author) / Kirschtowski, Sabine (author) / Seidel‐Morgenstern, Andreas (author) / Hamel, Christof (author)

Published in:

Chemie Ingenieur Technik ; 94 ; 760-765

Publication date:

2022-05-01

Size:

6 pages

ISSN:

0009-286X , 1522-2640

DOI:

https://doi.org/10.1002/cite.202100180

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Homogeneous rhodium catalysis , Hydroaminomethylation of 1‐decene , Reaction kinetics , Tandem reaction , Thermomorphic solvent system

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