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    Kinetic Modeling of Rhodium‐Catalyzed Reductive Amination of Undecanal in Different Solvent Systems

    New search for: Kirschtowski, Sabine
    New search for: Kadar, Christof
    New search for: Hamel, Christof

    The homogenously rhodium‐catalyzed reductive amination of 1‐undecanal was performed in two different thermomorphic solvent systems with the ligand Xantphos. The influences of partial pressure, temperature, methanol and catalyst concentration on the reaction were investigated. Based on a network analysis a kinetic model was derived and successfully parametrized for all studied solvent systems. Simulation results were found to be in good agreement with the experiments and allow a further process development and optimization.

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    Kinetic Modeling of Rhodium‐Catalyzed Reductive Amination of Undecanal in Different Solvent Systems

    New search for: Kirschtowski, Sabine
    New search for: Kadar, Christof
    New search for: Hamel, Christof

    The homogenously rhodium‐catalyzed reductive amination of 1‐undecanal was performed in two different thermomorphic solvent systems with the ligand Xantphos. The influences of partial pressure, temperature, methanol and catalyst concentration on the reaction were investigated. Based on a network analysis a kinetic model was derived and successfully parametrized for all studied solvent systems. Simulation results were found to be in good agreement with the experiments and allow a further process development and optimization.

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    Check access
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    Order at Subito €

    Kinetic Modeling of Rhodium‐Catalyzed Reductive Amination of Undecanal in Different Solvent Systems

    New search for: Kirschtowski, Sabine
    New search for: Kadar, Christof
    New search for: Hamel, Christof

    The homogenously rhodium‐catalyzed reductive amination of 1‐undecanal was performed in two different thermomorphic solvent systems with the ligand Xantphos. The influences of partial pressure, temperature, methanol and catalyst concentration on the reaction were investigated. Based on a network analysis a kinetic model was derived and successfully parametrized for all studied solvent systems. Simulation results were found to be in good agreement with the experiments and allow a further process development and optimization.

    Access

    Check access
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    Order at Subito €

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    Title:

    Kinetic Modeling of Rhodium‐Catalyzed Reductive Amination of Undecanal in Different Solvent Systems

    Contributors:

    Kirschtowski, Sabine (author) / Kadar, Christof (author) / Seidel‐Morgenstern, Andreas (author) / Hamel, Christof (author)

    Published in:

    Chemie Ingenieur Technik ; 92 ; 582-588

    Publication date:

    2020-05-01

    Size:

    7 pages

    ISSN:

    0009-286X , 1522-2640

    DOI:

    https://doi.org/10.1002/cite.201900135

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    Kinetic modeling , Reductive amination , Rhodium catalysis , Homogenous catalysis

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