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Zinc oxide varistor dielectric material and preparation method thereof
The invention relates to a zinc oxide varistor dielectric material, which is prepared from ZnO, Sb2O3, Bi2O3, a Mn-containing compound, a Co-containing compound, Ni2O3, In2O3, silver glass powder and Al (NO3) 3.9 H2O. The mole number of Sb2O3 accounts for 0.8%-1.05% of the mole number of ZnO, the mole number of Bi2O3 accounts for 0.55%-0.70% of the mole number of ZnO, the mole number of Mn ions in the Mn-containing compound accounts for 0.52%-0.84% of the mole number of ZnO, the mole number of Co ions in the Co-containing compound accounts for 0.90%-1.38% of the mole number of ZnO, the mole number of Ni2O3 accounts for 0.20%-0.40% of the mole number of ZnO, and the mole number of In2O3 accounts for 0.007%-0.010% of the mole number of ZnO; the weight of the silver glass powder is 0.08-0.1% of that of ZnO, and the weight of Al (NO3) 3.9 H2O is 0.025-0.030% of that of ZnO. The invention also provides a preparation method of the zinc oxide varistor dielectric material. The zinc oxide varistor dielectric material is good in pulse impact resistance, low in residual voltage under large current, capable of being sintered at medium and low temperatures and low in energy consumption.
一种氧化锌压敏电阻器介质材料,由ZnO、Sb2O3、Bi2O3、含Mn化合物、含Co化合物、Ni2O3、In2O3、银玻璃粉和Al(NO3)3.9H2O制成;Sb2O3的摩尔数是ZnO的0.8‑1.05%,Bi2O3的摩尔数是ZnO的0.55‑0.70%,含Mn化合物中Mn离子的摩尔数是ZnO的0.52‑0.84%,含Co化合物中Co离子的摩尔数是ZnO的0.90‑1.38%,Ni2O3的摩尔数是ZnO的0.20‑0.40%,In2O3的摩尔数是ZnO的0.007‑0.010%;银玻璃粉的重量是ZnO的0.08‑0.1%,Al(NO3)3.9H2O的重量是ZnO的0.025‑0.030%。本发明还提供上述氧化锌压敏电阻器介质材料的一种制备方法。本发明的氧化锌压敏电阻器介质材料脉冲冲击耐受能力良好,大电流下残压低,且可采用中低温烧结,能耗较低。
Zinc oxide varistor dielectric material and preparation method thereof
The invention relates to a zinc oxide varistor dielectric material, which is prepared from ZnO, Sb2O3, Bi2O3, a Mn-containing compound, a Co-containing compound, Ni2O3, In2O3, silver glass powder and Al (NO3) 3.9 H2O. The mole number of Sb2O3 accounts for 0.8%-1.05% of the mole number of ZnO, the mole number of Bi2O3 accounts for 0.55%-0.70% of the mole number of ZnO, the mole number of Mn ions in the Mn-containing compound accounts for 0.52%-0.84% of the mole number of ZnO, the mole number of Co ions in the Co-containing compound accounts for 0.90%-1.38% of the mole number of ZnO, the mole number of Ni2O3 accounts for 0.20%-0.40% of the mole number of ZnO, and the mole number of In2O3 accounts for 0.007%-0.010% of the mole number of ZnO; the weight of the silver glass powder is 0.08-0.1% of that of ZnO, and the weight of Al (NO3) 3.9 H2O is 0.025-0.030% of that of ZnO. The invention also provides a preparation method of the zinc oxide varistor dielectric material. The zinc oxide varistor dielectric material is good in pulse impact resistance, low in residual voltage under large current, capable of being sintered at medium and low temperatures and low in energy consumption.
一种氧化锌压敏电阻器介质材料,由ZnO、Sb2O3、Bi2O3、含Mn化合物、含Co化合物、Ni2O3、In2O3、银玻璃粉和Al(NO3)3.9H2O制成;Sb2O3的摩尔数是ZnO的0.8‑1.05%,Bi2O3的摩尔数是ZnO的0.55‑0.70%,含Mn化合物中Mn离子的摩尔数是ZnO的0.52‑0.84%,含Co化合物中Co离子的摩尔数是ZnO的0.90‑1.38%,Ni2O3的摩尔数是ZnO的0.20‑0.40%,In2O3的摩尔数是ZnO的0.007‑0.010%;银玻璃粉的重量是ZnO的0.08‑0.1%,Al(NO3)3.9H2O的重量是ZnO的0.025‑0.030%。本发明还提供上述氧化锌压敏电阻器介质材料的一种制备方法。本发明的氧化锌压敏电阻器介质材料脉冲冲击耐受能力良好,大电流下残压低,且可采用中低温烧结,能耗较低。
Zinc oxide varistor dielectric material and preparation method thereof
一种氧化锌压敏电阻器介质材料及其制备方法
ZHAO MINGHUI (Autor:in) / CHEN WENCHANG (Autor:in) / XIE DONGJU (Autor:in) / PENG YAQIAO (Autor:in) / YU QINGPING (Autor:in) / HUANG CHENYAO (Autor:in) / HU YONG (Autor:in) / LI XIAODAN (Autor:in) / CHEN YANZE (Autor:in) / SHEN JIANFENG (Autor:in)
06.09.2022
Patent
Elektronische Ressource
Chinesisch
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