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Preparation method of nano calcium carbonate for solar photovoltaic adhesive
The invention discloses a preparation method of nano calcium carbonate for solar photovoltaic adhesive, which comprises the following steps: adding cane sugar into lime milk, cooling the lime milk to 6-10 DEG C, and introducing mixed gas with high carbon dioxide concentration for carbonation reaction to obtain 1 # calcium carbonate suspension; adding hot water to dilute the suspension liquid, introducing mixed gas with low carbon dioxide concentration to carry out carbonation reaction, and adding lime milk into the suspension liquid to carry out calcium carbonate reaction to obtain 2 # calcium carbonate suspension liquid; adding sodium stearate into the suspension liquid for surface treatment, adding soluble inorganic metal salt, and finally respectively adding phosphoric triamide and phosphate for surface treatment; and dehydrating by a filter press, drying and crushing to obtain the nano calcium carbonate. The nano calcium carbonate with controllable particle size and more regular morphology is prepared by adopting a unique carbonation process, and the nano calcium carbonate can be endowed with more excellent mechanical properties; through special surface treatment, the aging resistance of the nano calcium carbonate filled photovoltaic adhesive is further improved.
本发明公开了一种太阳能光伏胶用纳米碳酸钙的制备方法,步骤包括:向石灰乳加入蔗糖,冷却石灰乳至6‑10℃,通入高二氧化碳浓度混合气体进行碳酸化反应,得1#碳酸钙悬浮液;再加入热水稀释悬浮液,通入低二氧化碳浓度混合气体进行碳酸化反应,同时向悬浮液中加入石灰乳进行碳酸钙反应,得到2#碳酸钙悬浮液;再向悬浮液加入硬脂酸钠表面处理,加入可溶性无机金属盐,最后分别加入磷酰三胺和磷酸酯进行表面处理;经压滤机脱水,干燥,粉碎,得纳米碳酸钙。本发明采用独特的碳酸化工艺来制备粒径可控和形貌更规整的纳米碳酸钙,可赋予纳米碳酸钙更优异的力学性能;经过特殊的表面处理进一步提高纳米碳酸钙填充光伏胶的耐老化性能。
Preparation method of nano calcium carbonate for solar photovoltaic adhesive
The invention discloses a preparation method of nano calcium carbonate for solar photovoltaic adhesive, which comprises the following steps: adding cane sugar into lime milk, cooling the lime milk to 6-10 DEG C, and introducing mixed gas with high carbon dioxide concentration for carbonation reaction to obtain 1 # calcium carbonate suspension; adding hot water to dilute the suspension liquid, introducing mixed gas with low carbon dioxide concentration to carry out carbonation reaction, and adding lime milk into the suspension liquid to carry out calcium carbonate reaction to obtain 2 # calcium carbonate suspension liquid; adding sodium stearate into the suspension liquid for surface treatment, adding soluble inorganic metal salt, and finally respectively adding phosphoric triamide and phosphate for surface treatment; and dehydrating by a filter press, drying and crushing to obtain the nano calcium carbonate. The nano calcium carbonate with controllable particle size and more regular morphology is prepared by adopting a unique carbonation process, and the nano calcium carbonate can be endowed with more excellent mechanical properties; through special surface treatment, the aging resistance of the nano calcium carbonate filled photovoltaic adhesive is further improved.
本发明公开了一种太阳能光伏胶用纳米碳酸钙的制备方法,步骤包括:向石灰乳加入蔗糖,冷却石灰乳至6‑10℃,通入高二氧化碳浓度混合气体进行碳酸化反应,得1#碳酸钙悬浮液;再加入热水稀释悬浮液,通入低二氧化碳浓度混合气体进行碳酸化反应,同时向悬浮液中加入石灰乳进行碳酸钙反应,得到2#碳酸钙悬浮液;再向悬浮液加入硬脂酸钠表面处理,加入可溶性无机金属盐,最后分别加入磷酰三胺和磷酸酯进行表面处理;经压滤机脱水,干燥,粉碎,得纳米碳酸钙。本发明采用独特的碳酸化工艺来制备粒径可控和形貌更规整的纳米碳酸钙,可赋予纳米碳酸钙更优异的力学性能;经过特殊的表面处理进一步提高纳米碳酸钙填充光伏胶的耐老化性能。
Preparation method of nano calcium carbonate for solar photovoltaic adhesive
一种太阳能光伏胶用纳米碳酸钙的制备方法
LIANG LIGE (Autor:in) / LU ZENGMENG (Autor:in) / FANG GUILI (Autor:in) / ZHOU XUAN (Autor:in) / LU CHUDIAN (Autor:in) / NING QIUJUN (Autor:in) / ZHU YONG (Autor:in)
19.03.2024
Patent
Elektronische Ressource
Chinesisch
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