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Metal organic framework material, preparation method thereof and application of metal organic framework material in water collection in air
The invention discloses a metal organic framework material, a preparation method thereof and application of the metal organic framework material in water collection in air. The metal organic framework material is formed by substitution coordination connection of an organic ligand and a Zr6 metal cluster. The organic ligand has the following chemical structure: # imgabs 0 # Zr6 metal cluster has the following chemical structure: # imgabs 1 #. The preparation method comprises the following steps: firstly, synthesizing the organic ligand containing five-membered sulfur heterocycle by taking 1, 1, 2, 2-tetra (thiophene-2-yl) ethylene as a raw material under specific and appropriate conditions; and then preparing the stable metal organic framework material with Zr6 metal clusters under specific and appropriate conditions. The synthesis and preparation method is simple in route, easy to operate and low in cost.
本发明公开了一种金属有机框架材料及其制备方法和在空气集水中的应用。金属有机框架材料由有机配体与Zr6金属团簇取代配位连接形成；有机配体具有如下所示化学结构：#imgabs0#Zr6金属团簇具有如下所示化学结构：#imgabs1#本发明制备方法首先以1,1,2,2‑四(噻吩‑2‑基)乙烯为原材料在特定且合适的条件下合成含五元硫杂环的有机配体，再与Zr6金属团簇在特定且合适的条件下制备稳定的金属有机框架材料。本发明合成和制备方法路线简单，操作简易，成本较低。
Metal organic framework material, preparation method thereof and application of metal organic framework material in water collection in air
The invention discloses a metal organic framework material, a preparation method thereof and application of the metal organic framework material in water collection in air. The metal organic framework material is formed by substitution coordination connection of an organic ligand and a Zr6 metal cluster. The organic ligand has the following chemical structure: # imgabs 0 # Zr6 metal cluster has the following chemical structure: # imgabs 1 #. The preparation method comprises the following steps: firstly, synthesizing the organic ligand containing five-membered sulfur heterocycle by taking 1, 1, 2, 2-tetra (thiophene-2-yl) ethylene as a raw material under specific and appropriate conditions; and then preparing the stable metal organic framework material with Zr6 metal clusters under specific and appropriate conditions. The synthesis and preparation method is simple in route, easy to operate and low in cost.
本发明公开了一种金属有机框架材料及其制备方法和在空气集水中的应用。金属有机框架材料由有机配体与Zr6金属团簇取代配位连接形成；有机配体具有如下所示化学结构：#imgabs0#Zr6金属团簇具有如下所示化学结构：#imgabs1#本发明制备方法首先以1,1,2,2‑四(噻吩‑2‑基)乙烯为原材料在特定且合适的条件下合成含五元硫杂环的有机配体，再与Zr6金属团簇在特定且合适的条件下制备稳定的金属有机框架材料。本发明合成和制备方法路线简单，操作简易，成本较低。
Metal organic framework material, preparation method thereof and application of metal organic framework material in water collection in air
金属有机框架材料及其制备方法和在空气集水中的应用
CHEN ZHIJIE (author) / MA SI (author) / XIONG ZHANGYI (author) / SHI LE (author)
2023-12-22
Patent
Electronic Resource
Chinese
IPC:
C08G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
,
Makromolekulare Verbindungen, anders erhalten als durch Reaktionen, an denen nur ungesättigte Kohlenstoff-Kohlenstoff-Bindungen beteiligt sind
/
B01J
Chemische oder physikalische Verfahren, z.B. Katalyse oder Kolloidchemie
,
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
/
E03B
Anlagen oder Verfahren zum Gewinnen, Sammeln oder Verteilen von Wasser
,
INSTALLATIONS OR METHODS FOR OBTAINING, COLLECTING, OR DISTRIBUTING WATER
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