A platform for research: civil engineering, architecture and urbanism
A platform for research: civil engineering, architecture and urbanism
Hydrophobic functional steel bar corrosion inhibitor as well as preparation method and application thereof
The invention belongs to the technical field of corrosion prevention and corrosion inhibition of reinforced concrete, and particularly relates to a hydrophobic functional steel bar corrosion inhibitor as well as a preparation method and application thereof. The hydrophobic functional steel bar corrosion inhibitor is formed by polymerizing a hydrophobic functional chain segment, a polyether chain segment and a corrosion-inhibiting functional chain segment, the hydrophobic functional chain segment is connected with the polyether chain segment through an ester bond, an amido bond or a silicon-oxygen bond, and the corrosion-inhibiting functional chain segment is connected with the polyether chain segment through-N,-NH or-O. The source monomer of the hydrophobic functional chain segment is a compound of organic acid or organic silicon of long-chain alkane or heterocyclic aromatic hydrocarbon. The source monomer of the anti-rust functional chain segment is one of micromolecular amino alcohol, a polyhydroxy compound and a polyamino compound. According to the hydrophobic functional steel bar corrosion inhibitor provided by the invention, through the design and preparation of the molecular structure of the novel corrosion inhibitor, the unification of a concrete hydrophobic anti-medium permeation group and a steel bar corrosion inhibition group is realized, and the overall corrosion resistance and long-term acting effect of the corrosion inhibitor on a reinforced concrete structure are enhanced.
本发明属于钢筋混凝土防腐阻锈技术领域，具体涉及一种疏水功能化钢筋阻锈剂、制备方法及其应用。所述疏水功能化钢筋阻锈剂由疏水功能链段、聚醚链段和阻锈功能链段聚合而成，其中疏水功能链段通过酯键、酰胺键或硅氧键与聚醚链段连接，阻锈功能链段通过‑N、‑NH或‑O与聚醚链段连接。所述疏水功能链段的来源单体为长链烷烃或杂环芳烃的有机酸或有机硅的化合物。所述阻锈功能链段的来源单体为小分子氨基醇、多羟基化合物、多氨基化合物中的一种。本发明提供的疏水功能化钢筋阻锈剂，通过新型阻锈剂分子结构的设计与制备，实现混凝土疏水抗介质渗透基团与钢筋阻锈基团的统一，增强阻锈剂对钢筋混凝土结构整体耐蚀性能及长期作用效果。
Hydrophobic functional steel bar corrosion inhibitor as well as preparation method and application thereof
The invention belongs to the technical field of corrosion prevention and corrosion inhibition of reinforced concrete, and particularly relates to a hydrophobic functional steel bar corrosion inhibitor as well as a preparation method and application thereof. The hydrophobic functional steel bar corrosion inhibitor is formed by polymerizing a hydrophobic functional chain segment, a polyether chain segment and a corrosion-inhibiting functional chain segment, the hydrophobic functional chain segment is connected with the polyether chain segment through an ester bond, an amido bond or a silicon-oxygen bond, and the corrosion-inhibiting functional chain segment is connected with the polyether chain segment through-N,-NH or-O. The source monomer of the hydrophobic functional chain segment is a compound of organic acid or organic silicon of long-chain alkane or heterocyclic aromatic hydrocarbon. The source monomer of the anti-rust functional chain segment is one of micromolecular amino alcohol, a polyhydroxy compound and a polyamino compound. According to the hydrophobic functional steel bar corrosion inhibitor provided by the invention, through the design and preparation of the molecular structure of the novel corrosion inhibitor, the unification of a concrete hydrophobic anti-medium permeation group and a steel bar corrosion inhibition group is realized, and the overall corrosion resistance and long-term acting effect of the corrosion inhibitor on a reinforced concrete structure are enhanced.
本发明属于钢筋混凝土防腐阻锈技术领域，具体涉及一种疏水功能化钢筋阻锈剂、制备方法及其应用。所述疏水功能化钢筋阻锈剂由疏水功能链段、聚醚链段和阻锈功能链段聚合而成，其中疏水功能链段通过酯键、酰胺键或硅氧键与聚醚链段连接，阻锈功能链段通过‑N、‑NH或‑O与聚醚链段连接。所述疏水功能链段的来源单体为长链烷烃或杂环芳烃的有机酸或有机硅的化合物。所述阻锈功能链段的来源单体为小分子氨基醇、多羟基化合物、多氨基化合物中的一种。本发明提供的疏水功能化钢筋阻锈剂，通过新型阻锈剂分子结构的设计与制备，实现混凝土疏水抗介质渗透基团与钢筋阻锈基团的统一，增强阻锈剂对钢筋混凝土结构整体耐蚀性能及长期作用效果。
Hydrophobic functional steel bar corrosion inhibitor as well as preparation method and application thereof
一种疏水功能化钢筋阻锈剂、制备方法及其应用
CAI JINGSHUN (author) / MU SONG (author) / HONG JINXIANG (author) / MA QI (author) / LIU JIANZHONG (author) / ZHUANG ZHIJIE (author) / LIU GUANGYAN (author) / GUO ZHENG (author)
2024-03-29
Patent
Electronic Resource
Chinese
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