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Lead-free, lithium-free and re-firing-free overglaze silk screen pigment for ceramic and preparation method of overglaze silk screen pigment
The invention discloses a lead-free lithium-free re-firing-free overglaze silk screen pigment for ceramics, which comprises a colorant and a flux in a weight ratio of (8-30%): (70-92%), the flux is prepared from the following raw material components in parts by weight: 35 to 75 parts of silicon dioxide (SiO2), 3 to 20 parts of diboron trioxide (B2O3), 1.5 to 10 parts of aluminum oxide (Al2O3), 1 to 12 parts of zirconium silicate (ZrSiO4), 1 to 8.5 parts of bismuth trioxide (Bi2O3), 1 to 10 parts of fluorine F and acidic oxide. The toner is a lead-free toner. The preparation method comprises the following steps: S1, preparing a flux; and S2, mixing a colorant with the prepared flux to obtain the powdery pigment. The color agent and the flux are mixed through a dry ball milling process to achieve the same effect as re-burning heat treatment in the prior art, so that in the pigment preparation process, the physical and chemical performance improvement process of high-temperature re-burning heat treatment is omitted, the quality and the production efficiency of a pigment product are improved, and the production cost is reduced.
本发明公开一种无铅无锂免复烧的陶瓷用釉上丝网颜料，包括色剂和熔剂，色剂和熔剂的重量比为8～30％：70～92％；熔剂按照重量份数计，其原料组成包括以下组分：二氧化硅SiO235～75份、三氧化二硼B2O33～20份、氧化铝Al2O31.5～10份、硅酸锆ZrSiO41～12份、三氧化二铋Bi2O31～8.5份、氟F 1～10份以及酸性氧化物；色剂为无铅色剂。制备方法，包括以下步骤：S1、制备熔剂；S2、将色剂与上述制备的熔剂进行混合，得到粉状颜料。通过干法球磨工艺将色剂与熔剂混合，用以达到与现有技术中经复烧热处理同等效果，从而，在颜料制备过程中，省去了高温复烧热处理这个理化性能绩化工艺，以提高颜料制品的质量及生产效率，降低了生产成本。
Lead-free, lithium-free and re-firing-free overglaze silk screen pigment for ceramic and preparation method of overglaze silk screen pigment
The invention discloses a lead-free lithium-free re-firing-free overglaze silk screen pigment for ceramics, which comprises a colorant and a flux in a weight ratio of (8-30%): (70-92%), the flux is prepared from the following raw material components in parts by weight: 35 to 75 parts of silicon dioxide (SiO2), 3 to 20 parts of diboron trioxide (B2O3), 1.5 to 10 parts of aluminum oxide (Al2O3), 1 to 12 parts of zirconium silicate (ZrSiO4), 1 to 8.5 parts of bismuth trioxide (Bi2O3), 1 to 10 parts of fluorine F and acidic oxide. The toner is a lead-free toner. The preparation method comprises the following steps: S1, preparing a flux; and S2, mixing a colorant with the prepared flux to obtain the powdery pigment. The color agent and the flux are mixed through a dry ball milling process to achieve the same effect as re-burning heat treatment in the prior art, so that in the pigment preparation process, the physical and chemical performance improvement process of high-temperature re-burning heat treatment is omitted, the quality and the production efficiency of a pigment product are improved, and the production cost is reduced.
本发明公开一种无铅无锂免复烧的陶瓷用釉上丝网颜料，包括色剂和熔剂，色剂和熔剂的重量比为8～30％：70～92％；熔剂按照重量份数计，其原料组成包括以下组分：二氧化硅SiO235～75份、三氧化二硼B2O33～20份、氧化铝Al2O31.5～10份、硅酸锆ZrSiO41～12份、三氧化二铋Bi2O31～8.5份、氟F 1～10份以及酸性氧化物；色剂为无铅色剂。制备方法，包括以下步骤：S1、制备熔剂；S2、将色剂与上述制备的熔剂进行混合，得到粉状颜料。通过干法球磨工艺将色剂与熔剂混合，用以达到与现有技术中经复烧热处理同等效果，从而，在颜料制备过程中，省去了高温复烧热处理这个理化性能绩化工艺，以提高颜料制品的质量及生产效率，降低了生产成本。
Lead-free, lithium-free and re-firing-free overglaze silk screen pigment for ceramic and preparation method of overglaze silk screen pigment
一种无铅无锂免复烧的陶瓷用釉上丝网颜料及制备方法
XIE FENGYI (author) / XIAO ZHENG (author) / XIE HAIMING (author)
2024-12-20
Patent
Electronic Resource
Chinese
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