Inhibition of mild oxidation of styrene epoxide by oxygen in acidic alcohol solution by halide ions: Fid-Bau Portal

Fachinformationsdienst BAUdigital

A platform for research: civil engineering, architecture and urbanism

Inhibition of mild oxidation of styrene epoxide by oxygen in acidic alcohol solution by halide ions

Petrov, L. V. / Solyanikov, V. M.

Abstract Alkyl-substituted ammonium and lithium chlorides inhibit oxygen consumption in the oxidation of styrene epoxide in the presence of p-toluenesulfonic acid in a tert-butanol-chlorobenzene (9: 1, v/v) solution at 343 K. The inhibitory effect of chlorides is the same for tetramethylammonium, benzyltriethylammonium, and lithium chlorides, thus suggesting the inhibiting action of the anion. The oxidation inhibition effect of ammonium fluoride is ∼2.5 times as strong as that of the chlorides. The main finding of the study is the simultaneous retardation of oxidation and acid-catalyzed heterolytic epoxide consumption by the chloride and iodide anions.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Inhibition of mild oxidation of styrene epoxide by oxygen in acidic alcohol solution by halide ions

Petrov, L. V. / Solyanikov, V. M.

Abstract Alkyl-substituted ammonium and lithium chlorides inhibit oxygen consumption in the oxidation of styrene epoxide in the presence of p-toluenesulfonic acid in a tert-butanol-chlorobenzene (9: 1, v/v) solution at 343 K. The inhibitory effect of chlorides is the same for tetramethylammonium, benzyltriethylammonium, and lithium chlorides, thus suggesting the inhibiting action of the anion. The oxidation inhibition effect of ammonium fluoride is ∼2.5 times as strong as that of the chlorides. The main finding of the study is the simultaneous retardation of oxidation and acid-catalyzed heterolytic epoxide consumption by the chloride and iodide anions.

Inhibition of mild oxidation of styrene epoxide by oxygen in acidic alcohol solution by halide ions

Petrov, L. V. / Solyanikov, V. M.

Abstract Alkyl-substituted ammonium and lithium chlorides inhibit oxygen consumption in the oxidation of styrene epoxide in the presence of p-toluenesulfonic acid in a tert-butanol-chlorobenzene (9: 1, v/v) solution at 343 K. The inhibitory effect of chlorides is the same for tetramethylammonium, benzyltriethylammonium, and lithium chlorides, thus suggesting the inhibiting action of the anion. The oxidation inhibition effect of ammonium fluoride is ∼2.5 times as strong as that of the chlorides. The main finding of the study is the simultaneous retardation of oxidation and acid-catalyzed heterolytic epoxide consumption by the chloride and iodide anions.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Document information

Title:

Inhibition of mild oxidation of styrene epoxide by oxygen in acidic alcohol solution by halide ions

Contributors:

Petrov, L. V. (author) / Solyanikov, V. M. (author)

Published in:

Petroleum Chemistry ; 52 ; 327-334

Publication date:

2012-09-01

Size:

8 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554411205009X

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Epoxide , LiCl , Petroleum Chemistry , Tert Butanol , Ammonium Fluoride Chemistry , Industrial Chemistry/Chemical Engineering

Similar titles

Inhibition of the oxidation of styrene epoxide by potassium iodide and bromide in an acidic solution

Petrov, L. V. / Solyanikov, V. M. | Springer Verlag | 2010

Oxidation of the Styrene Epoxide–Sulfuric Acid Binary System in an Alcohol Solution

Petrov, L. V. / Spirin, M. G. / Solyanikov, V. M. | Springer Verlag | 2023

Mild oxidation of styrene epoxide in the presence of trace perchloric acid

Petrov, L. V. / Solyanikov, V. M. | Springer Verlag | 2011

Inhibition of mild steel corrosion in acidic medium using synthetic and naturally occurring polymers and synergistic halide additives

Umoren, S. A. / Ogbobe, O. / Igwe, I. O. et al. | British Library Online Contents | 2008

Corrosion inhibition of mild steel in acidic solution by some oxo-triazole derivatives

Tao, Z. / Zhang, S. / Li, W. et al. | British Library Online Contents | 2009