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Inhibition of the oxidation of styrene epoxide by potassium iodide and bromide in an acidic solution

Petrov, L. V. / Solyanikov, V. M.

Abstract The inhibiting action of potassium iodide and bromide on the oxidation of the binary system of styrene epoxide + p-toluenesulfonic acid and on the hydroperoxide decomposition in the presence of the binary system was revealed. The inhibition mechanism is complex. During the course of the inhibition, the active form of the inhibitor is regenerated, which interacts, according to the kinetic data, with the transient species formed in the binary mixture.

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Inhibition of the oxidation of styrene epoxide by potassium iodide and bromide in an acidic solution

Petrov, L. V. / Solyanikov, V. M.

Abstract The inhibiting action of potassium iodide and bromide on the oxidation of the binary system of styrene epoxide + p-toluenesulfonic acid and on the hydroperoxide decomposition in the presence of the binary system was revealed. The inhibition mechanism is complex. During the course of the inhibition, the active form of the inhibitor is regenerated, which interacts, according to the kinetic data, with the transient species formed in the binary mixture.

Inhibition of the oxidation of styrene epoxide by potassium iodide and bromide in an acidic solution

Petrov, L. V. / Solyanikov, V. M.

Abstract The inhibiting action of potassium iodide and bromide on the oxidation of the binary system of styrene epoxide + p-toluenesulfonic acid and on the hydroperoxide decomposition in the presence of the binary system was revealed. The inhibition mechanism is complex. During the course of the inhibition, the active form of the inhibitor is regenerated, which interacts, according to the kinetic data, with the transient species formed in the binary mixture.

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Title:

Inhibition of the oxidation of styrene epoxide by potassium iodide and bromide in an acidic solution

Contributors:

Petrov, L. V. (author) / Solyanikov, V. M. (author)

Published in:

Petroleum Chemistry ; 50 ; 154-157

Publication date:

2010-03-01

Size:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554411002012X

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Binary System , MeCN , AIBN , Petroleum Chemistry , Ethylbenzene Chemistry , Industrial Chemistry/Chemical Engineering

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