Immobilized ionic liquids based on molybdenum- and tungsten-containing heteropoly acids: Structure and catalytic properties in thiophene oxidation: Fid-Bau Portal

Immobilized ionic liquids based on molybdenum- and tungsten-containing heteropoly acids: Structure and catalytic properties in thiophene oxidation

Tarkhanova, I. G. / Anisimov, A. V. / Buryak, A. K. / Bryzhin, A. A. / Ali-Zade, A. G. / Akopyan, A. V. / Zelikman, V. M.

Abstract

Abstract Comparative analysis of heterogeneous catalysts for the peroxide oxidation of thiophene is conducted. The catalysts are imidazole ionic liquids (ILs) containing anions of phosphomolybdic and phosphotungstic acids immobilized on mineral supports. Immobilization is implemented by the covalent bonding of an IL fragment to a silica surface or by adsorption on alumina. The catalysts are active not only in the model oxidation of thiophene in isooctane, but also in the desulfurization of a straight-run diesel fraction and the “synthetic crude oil” derived from oil shale.

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Immobilized ionic liquids based on molybdenum- and tungsten-containing heteropoly acids: Structure and catalytic properties in thiophene oxidation

Tarkhanova, I. G. / Anisimov, A. V. / Buryak, A. K. / Bryzhin, A. A. / Ali-Zade, A. G. / Akopyan, A. V. / Zelikman, V. M.

Abstract

Immobilized ionic liquids based on molybdenum- and tungsten-containing heteropoly acids: Structure and catalytic properties in thiophene oxidation

Tarkhanova, I. G. / Anisimov, A. V. / Buryak, A. K. / Bryzhin, A. A. / Ali-Zade, A. G. / Akopyan, A. V. / Zelikman, V. M.

Abstract

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Title:

Immobilized ionic liquids based on molybdenum- and tungsten-containing heteropoly acids: Structure and catalytic properties in thiophene oxidation

Contributors:

Tarkhanova, I. G. (author) / Anisimov, A. V. (author) / Buryak, A. K. (author) / Bryzhin, A. A. (author) / Ali-Zade, A. G. (author) / Akopyan, A. V. (author) / Zelikman, V. M. (author)

Published in:

Petroleum Chemistry ; 57 ; 859-867

Publication date:

2017-09-23

Size:

9 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544117100164

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

thiophene oxidation , hydrogen peroxide , immobilized metal-containing ionic liquids , phosphomolybdic and phosphotungstic heteropoly acids Chemistry , Industrial Chemistry/Chemical Engineering

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