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Oxidation of unsaturated compounds in ionic liquids with the use of cyclodextrin-containing catalytic systems
Abstract The Wacker oxidation of alkenes-1 in ionic liquids catalyzed by a system containing palladium, and copper complexes and β-cyclodextrins was studied. It was shown that the use of β-cyclodextrins substantially increases the oxidation rate in biphasic systems olefin/ionic liquid. It was found that the proposed catalytic systems possess substrate selectivity, which is determined by the structure of a receptor molecule.
Oxidation of unsaturated compounds in ionic liquids with the use of cyclodextrin-containing catalytic systems
Abstract The Wacker oxidation of alkenes-1 in ionic liquids catalyzed by a system containing palladium, and copper complexes and β-cyclodextrins was studied. It was shown that the use of β-cyclodextrins substantially increases the oxidation rate in biphasic systems olefin/ionic liquid. It was found that the proposed catalytic systems possess substrate selectivity, which is determined by the structure of a receptor molecule.
Oxidation of unsaturated compounds in ionic liquids with the use of cyclodextrin-containing catalytic systems
Andreeva, L. V. (author) / Maksimov, A. L. (author) / Zhuchkova, A. Ya. (author) / Predeina, V. V. (author) / Filippova, T. Yu. (author) / Karakhanov, E. A. (author)
Petroleum Chemistry ; 47 ; 331-336
2007-09-01
6 pages
Article (Journal)
Electronic Resource
English
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