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Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic and preparation method thereof
The invention provides a Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic. The structural formula of the Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic is Tb3Al5-xSiyTizO12, wherein y plus z is equal to x, and the numerical areas of x, y and z are as follows: x is greater than or equal to 0.01 and less than or equal to 0.06, y is greater than or equal to 0 and less than or equal to 0.06, and z is greater than or equal to 0 and less than or equal to 0.06. The preparation method of the Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic comprises the following steps: proportioning raw materials according to the structural formula Tb3Al5-xSiyTizO12, adding 0.3wt%-0.7wt% of tetraethyl orthosilicate and performing ball milling, drying, sieving and tableting; and then applying isostatic cool pressure of above 150MPa for pressing into a green body; pre-sintering to remove organic components, and then putting the pre-sintered green body into a sintering furnace for sintering to obtain the Tb3Al5-xSiyTizO12 transparent ceramic. The Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic has relatively high optical transmittance within the visible-near infrared waveband and is capable of maintaining the relatively high Verdet constant of the original matrix TAG; the transparent ceramic has the advantages of simple preparation process, low cost, short preparation period and the like.
Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic and preparation method thereof
The invention provides a Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic. The structural formula of the Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic is Tb3Al5-xSiyTizO12, wherein y plus z is equal to x, and the numerical areas of x, y and z are as follows: x is greater than or equal to 0.01 and less than or equal to 0.06, y is greater than or equal to 0 and less than or equal to 0.06, and z is greater than or equal to 0 and less than or equal to 0.06. The preparation method of the Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic comprises the following steps: proportioning raw materials according to the structural formula Tb3Al5-xSiyTizO12, adding 0.3wt%-0.7wt% of tetraethyl orthosilicate and performing ball milling, drying, sieving and tableting; and then applying isostatic cool pressure of above 150MPa for pressing into a green body; pre-sintering to remove organic components, and then putting the pre-sintered green body into a sintering furnace for sintering to obtain the Tb3Al5-xSiyTizO12 transparent ceramic. The Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic has relatively high optical transmittance within the visible-near infrared waveband and is capable of maintaining the relatively high Verdet constant of the original matrix TAG; the transparent ceramic has the advantages of simple preparation process, low cost, short preparation period and the like.
Si/Ti doped terbium aluminum garnet Faraday magneto-optical rotation transparent ceramic and preparation method thereof
ZHOU SHENGMING (Autor:in) / CHEN CHONG (Autor:in) / FENG YUE (Autor:in) / LIN HUI (Autor:in) / YI XUEZHUAN (Autor:in) / ZHANG SHUAI (Autor:in) / TANG YANRU (Autor:in)
13.05.2015
Patent
Elektronische Ressource
Englisch
IPC:
C04B
Kalk
,
LIME
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